It wouldn't buy at that price. You are buying the shares from the market, not from Commsec, so you'll get filled at whatever price is available in the market at the time. As it shows on your screenshot, it says that is an order 'estimate'. They seem to be using the last price in their calculation for their estimate, but that's not really accurate. However, you should note that the market depth, as shown in your screenshot, could change at any moment as other people are buying and selling all the time. So by the time you click the buy button and your order executes, those prices may have changed and you may get filled at a different price, maybe higher price, maybe lower price. Hence why they say it is an 'estimate'.
However if you want to be sure, then place a limit order for $54.33 instead, as that will ensure you pay no more than that much. But there is the risk that you may not get filled at all, if for example, someone else buys all the shares available at $54.33 moments before you click the buy button.